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A Pawn can certainly attack a King (technically, Kings are not captured, but mated, since the game is over when the King is in a position where it can not avoid being captured, and the actual capture is not made). If a Pawn is in position to attack a King, then the King is in check and must be moved if possible to an unattacked square or the Pawn must be captured; if neither is possible, then it is checkmate.